This book provides an outline of theoretical concepts and their experimental verification in studies of self-organization phenomena in chemical systems, as they emerged in the mid-20th century and have evolved since. Presenting essays on selected topics, it was prepared by authors who have made profound contributions to the field. Traditionally, physical chemistry has been concerned with interactions between atoms and molecules that produce a variety of equilibrium structures - or the 'dead' order - in a stationary state. But biological cells exhibit a different 'living' kind of order, prompting E. Schroedinger to pose his famous question "What is life?" in 1943. Through an unprecedented theoretical and experimental development, it was later revealed that biological self-organization phenomena are in complete agreement with the laws of physics, once they are applied to a special class of thermodynamically open systems and non-equilibrium states. This knowledge has in turn led to the design and synthesis of simple inorganic systems capable of self-organization effects. These artificial 'living organisms' are able to operate on macroscopic to microscopic scales, even down to single-molecule machines. In the future, such research could provide a basis for a technological breakthrough, comparable in its impact with the invention of lasers and semiconductors. Its results can be used to control natural chemical processes, and to design artificial complex chemical processes with various functionalities. The book offers an extensive discussion of the history of research on complex chemical systems and its future prospects.

This textbook is based on a lecture course in synergetics given at the University of Moscow. In this second of two volumes, we discuss the emergence and properties of complex chaotic patterns in distributed active systems. Such patterns can be produced autonomously by a system, or can result from selective amplification of fluctuations caused by external weak noise. Although the material in this book is often described by refined mathematical theories, we have tried to avoid a formal mathematical style. Instead of rigorous proofs, the reader will usually be offered only "demonstrations" (the term used by Prof. V. I. Arnold) to encourage intuitive understanding of a problem and to explain why a particular statement seems plausible. We also refrained from detailing concrete applications in physics or in other scientific fields, so that the book can be used by students of different disciplines. While preparing the lecture course and producing this book, we had intensive discussions with and asked the advice of Prof. V. I. Arnold, Prof. S. Grossmann, Prof. H. Haken, Prof. Yu. L. Klimontovich, Prof. R. L. Stratonovich and Prof. Ya.

The second edition of this volume has been extensively revised. A different version of Chap. 7, reflecting recent significant progress in understanding of spatiotempo ral chaos, is now provided. Much new material has been included in the sections dealing with intermittency in birth-death models and noise-induced phase transi tions. A new section on control of chaotic behavior has been added to Chap. 6. The subtitle of the volume has been changed to better reflect its contents. We acknowledge stimulating discussions with H. Haken and E. Scholl and are grateful to our colleagues M. Bar, D. Battogtokh, M. Eiswirth, M. Hildebrand, K. Krischer, and V. Tereshko for their comments and assistance. We thank M. Lubke for her help in producing new figures for this volume. Berlin and Moscow A. s. Mikhailov April 1996 A. Yu. Loskutov Preface to the First Edition This textbook is based on a lecture course in synergetics given at the University of Moscow. In this second of two volumes, we discuss the emergence and properties of complex chaotic patterns in distributed active systems. Such patterns can be produced autonomously by a system, or can result from selective amplification of fluctuations caused by external weak noise."

This book gives an introduction to the mathematical theory of cooperative behavior in active systems of various origins, both natural and artificial. It is based on a lecture course in synergetics which I held for almost ten years at the University of Moscow. The first volume deals mainly with the problems of pattern fonnation and the properties of self-organized regular patterns in distributed active systems. It also contains a discussion of distributed analog information processing which is based on the cooperative dynamics of active systems. The second volume is devoted to the stochastic aspects of self-organization and the properties of self-established chaos. I have tried to avoid delving into particular applications. The primary intention is to present general mathematical models that describe the principal kinds of coopera tive behavior in distributed active systems. Simple examples, ranging from chemical physics to economics, serve only as illustrations of the typical context in which a particular model can apply. The manner of exposition is more in the tradition of theoretical physics than of in mathematics: Elaborate fonnal proofs and rigorous estimates are often replaced the text by arguments based on an intuitive understanding of the relevant models. Because of the interdisciplinary nature of this book, its readers might well come from very diverse fields of endeavor. It was therefore desirable to minimize the re quired preliminary knowledge. Generally, a standard university course in differential calculus and linear algebra is sufficient."

Using simple models this book shows how we can gain insights into the behavior of complex systems. It is devoted to the discussion of functional self-organization in large populations of interacting active elements. The authors have chosen a series of models from physics, biochemistry, biology, sociology and economics, and systematically discuss their general properties. The book addresses researchers and graduate students in a variety of disciplines.

This book shows how, by rather simple models, we can gain remarkable insights into the behavior of complex systems. It is devoted to the discussion of functional self-organization in large populations of interacting active elements. The possible forms of self-organization in such systems range from coherent collective motions in the physical coordinate space to the mutual synchronization of internal dynamics, the development of coherently operating groups, the rise of hierarchical structures, and the emergence of dynamical networks. Such processes play an important role in biological and social phenomena. The authors have chosen a series of models from physics, biochemistry, biology, sociology and economics, and will systematically discuss their general properties. The book addresses researchers and graduate students in a variety of disciplines, such as physics, chemistry, biology and the social sciences.

This second review volume is a follow-up to the book "Engineering of Chemical Complexity" that appeared in 2013. Co-edited by the Nobel laureate Gerhard Ertl, this book provides a broad perspective over the current research aimed at understanding, the design and control of complex chemical systems of various origins, on the scales ranging from single molecules and nano-phenomena to macroscopic chemical reactors. Self-organization behavior and emergence of coherent collective dynamics in reaction-diffusion systems, in active soft matter and biochemical networks are discussed. Special attention is paid to applications in cell biology, to molecular motors and microfluidics effects. The reviews, prepared by leading international experts from the EU, USA, Russia and Japan, together yield a fascinating picture of a rapidly developing research discipline that brings chemical engineering to new frontiers.

This review volume, co-edited by Nobel laureate G Ertl, provides a broad overview on current studies in the understanding of design and control of complex chemical systems of various origins, on scales ranging from single molecules and nano-phenomena to macroscopic chemical reactors. Self-organizational behavior and the emergence of coherent collective dynamics in reaction diffusion systems, reactive soft matter and chemical networks are covered. Special attention is paid to the applications in molecular cell biology and to the problems of biological evolution, synthetic biology and design of artificial living cells. Starting with a detailed introduction on the history of research on complex chemical systems, its current state of the art and perspectives, the book comprises 19 chapters that survey the current progress in particular research fields. The reviews, prepared by leading international experts, yield together a fascinating picture of a rapidly developing research discipline that brings chemical engineering to new frontiers.